Aqueous Surfactant Washing of Residual Oil Contamination from Sandy Soil   总被引：2，自引：0，他引：2  

Carolina C. Ang  Abdul S. Abdul 《Ground Water Monitoring & Remediation》1991,11(2):121-127

A laboratory study was conducted to determine the efficiency of different aqueous concentrations of an alcohol ethoxylate surfactant in washing residual levels of an oil [automatic transmission fluid (ATF)] from sandy soil. Five glass columns packed with the soil were prepared in a manner that simulated conditions leading to residual saturation in an actual oil leak. Each of four columns was washed continuously with 28 pore volumes of solution by pumping either 0.0 percent (water), 0.5 percent, 1.0 percent, or 2.0 percent aqueous surfactant solutions through the columns. The fifth column was washed intermittently with 28 pore volumes of a 1.0 percent surfactant solution. Water washed only 25.5 percent of the ATF from the column soil, while the 0.5 percent, 1 percent, and 2 percent surfactant solutions washed 55 percent, 60 percent, and 72.8 percent of the ATF, respectively. The distribution of the ATF remaining in the column after washing showed that the ATF removed by water was mainly from the outlet side of the column, while the ATF removed by the 2.0 percent surfactant solution was mainly from the inlet side of the column. This observation indicated that different mechanisms were involved; namely, the displacement of oil through the soil-pore space, the dispersion of oil due to reduced surface tension, and the solubilization of oil by surfactant micelles. In the case of water, the displacement of oil was the main washing mechanism, while all three mechanisms were operative during surfactant washing. ATF dispersion and solubilization were improved at higher surfactant concentrations. The column that was washed intermittently to pulse ATF from dead end pores did not show a significant improvement over the column that was continuously washed with the same 1.0 percent surfactant solution. The results show promising potential for application in the field and will be further investigated in a two-dimensional model aquifer.  相似文献   

Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment,southeast of Buenos Aires Province,Argentina     

Carolina Calvi  Daniel Martinez  Cristina Dapeña  Florencia Gutheim 《Environmental Earth Sciences》2016,75(6):534

  相似文献   

A grain-size correction for metal pollution indexes in river sediments     

Thomas Vincent Gloaguen  Paula Núbia Soares Dalto Motta  Carolina Fonseca Couto 《国际泥沙研究》2021,36(3):362-372

According to the List of Hazardous Substances of the Agency of the Toxic Substances and Disease Registry(ATSDR 2017),some metallic elements such as Pb or Cd are still considered as the most polluting elements in the world.These elements accumulate in sediments,and there are various methods available that differentiate lithogenic sources from anthropogenic sources.For that,the natural geochemical background is required,however,its definition is far from unanimous:it can be a global or local value,single or statistically estimated value,depending on the studies.Our study is focused on the Suba
e River in the state of Bahia,Northeastern Brazil,which was historically contaminated by lead metallurgy.The river sediments were sampled at 21 locations:one at the discharge point of the plant's rainwater basin,ten upstream,and ten downstream.The total contents of Fe,Ti,Mn,Pb,Zn,Cu,Cr,particle-size distribution,and organic matter were analyzed.The conventional geochemical indexes,i.e.,the pollution degree(mCd),pollution load index,and enrichment factor indicated contamination by Zn,Pb,Cr,and Cu.Then,a new enrichment factor is introduced,assuming that the sediments come from erosion of soils in the watershed.After obtaining the natural concentrations of metals in the clay,silt,and sand fractions of uncontaminated reference soils,we corrected the pollution indexes by calculating a new individual background in each sediment sample,according to its grain size distribution.This new approach provided more precise indexes in the assessment of sediment pollution,by highlighting higher contamination of Zn and Pb(around 50%)and at the same time the absence of Cr and Cu contamination,two metals not involved with the metallurgical activity.  相似文献   

The Na i D resonance lines in main-sequence late-type stars     

Rodrigo F. Díaz  Carolina Cincunegui  Pablo J. D. Mauas 《Monthly notices of the Royal Astronomical Society》2007,378(3):1007-1018

We study the sodium D lines (D1: 5895.92 Å; D2: 5889.95 Å) in late-type dwarf stars. The stars have spectral types between F6 and M5.5 ( B − V between 0.457 and 1.807) and metallicity between  [Fe/H]=−0.82  and 0.6. We obtained medium-resolution echelle spectra using the 2.15-m telescope at the Argentinian observatory Complejo Astronómico El Leoncito (CASLEO). The observations have been performed periodically since 1999. The spectra were calibrated in wavelength and in flux. A definition of the pseudo-continuum level is found for all our observations. We also define a continuum level for calibration purposes. The equivalent width of the D lines is computed in detail for all our spectra and related to the colour index ( B − V ) of the stars. When possible, we perform a careful comparison with previous studies. Finally, we construct a spectral index  ( R '_D)  as the ratio between the flux in the D lines and the bolometric flux. We find that, once corrected for the photospheric contribution, this index can be used as a chromospheric activity indicator in stars with a high level of activity. Additionally, we find that combining some of our results, we obtain a method to calibrate in flux stars of unknown colour.  相似文献   

Using historical source data to understand urban flood risk: a socio-hydrological modelling application at Gregório Creek,Brazil     

Ana Carolina Sarmento Buarque  Namrata Bhattacharya-Mis  Maria Clara Fava  Felipe Augusto Arguello de Souza  Eduardo Mario Mendiondo 《水文科学杂志》2020,65(7):1075-1083

ABSTRACT

The city of São Carlos, state of São Paulo, Brazil, has a historical coexistence between society and floods. Unplanned urbanization in this area is a representative feature of how Brazilian cities have developed, undermining the impact of natural hazards. The Gregório Creek catchment is an enigma of complex dynamics concerning the relationship between humans and water in Brazilian cities. Our hypothesis is that social memory of floods can improve future resilience. In this paper we analyse flood risk dynamics in a small urban catchment, identify the impacts of social memory on building resilience and propose measures to reduce the risk of floods. We applied a socio-hydrological model using data collected from newspapers from 1940 to 2018. The model was able to elucidate human–water processes in the catchment and the historical source data proved to be a useful tool to fill gaps in the data in small urban basins.  相似文献   

Long term variation in rainfall erosivity in Uruguay: a preliminary Fournier approach     

Carolina Munka  Gabriela Cruz  Ruben Mario Caffera 《GeoJournal》2007,70(4):257-262

In order to explore the consequences of precipitation increase on soil erosion in Uruguay, the monthly Fournier Index (FI) and the annual Modified Fournier Index (MFI) were developed as a preliminary approach, covering consecutive decadal periods from 1931 to 2000. Rainfall data were used from 13 stations distributed all over the country. MFI shows a decrease in the 1940s, an increase during the 1950s, then a little decrease during the 1960s and 1970s and an increase in the 1980s, remaining near these last values during the 1990s. FI behavior in July and October in the last two decades shows a decrease in the Northeast region of the country—the region with highest annual precipitation—and a slight increase over the Southeast—the region with the lowest annual precipitation and the only region with a winter rainfall maximum. For the core months of winter and early spring there is a decline in erosivity in the Northeast, but an increase in the Southeast. January shows erosivity decreasing in the South during the last two decades. In April there is a peak in precipitation variability all across the country. FI shows an early increase during the 1940s in the Northwest, and generally very low values during the 1970s, with the return of high values in the 1990s, especially in the Northern corner. Results pose a challenge in order to improve research on the erosion problem, since the main source of freshwater nationwide remains surface river flow, which is prone to higher turbidity problems in areas of high soil erosion.  相似文献   

Joint effects of climate warming and exotic litter (Eucalyptus globulus Labill.) on stream detritivore fitness and litter breakdown     

Francisco Correa-Araneda  Luz Boyero  Ricardo Figueroa  Carolina Sánchez  Roberto Abdala  Antonio Ruiz-García  Manuel A. S. Graça 《Aquatic Sciences - Research Across Boundaries》2015,77(2):197-205

  相似文献   

Atacama Field Campaign: laboratory and in-situ measurements for remote sensing applications     

Cristian Mattar  Andrés Santamaría-Artigas  Flavio Ponzoni  Cibele T. Pinto  Carolina Barrientos  Glynn Hulley 《International Journal of Digital Earth》2019,12(1):43-61

This work presents the preliminary results of the first field calibration campaign performed in the Atacama Desert, Chile, between the 18 and 22 August 2014, called the Atacama Field Campaign (ATAFIC 2014). In situ measurements were performed in order to spectrally characterize the surface reflectance spectra between 0.3 and 2.5?µm, radiometric temperature (8.0–14.0?µm) and atmospheric measurements. A soil sample was collected and analyzed using Fourier Transform Infrared Spectroscopy and X-Ray Diffraction techniques to characterize the surface reflectance spectra and mineralogical composition, respectively. ASTER land surface emissivity in addition to GOES, MODIS and Landsat-8 land surface temperature (LST) were also used. Results showed that the spectral features of the Atacama soil and the characteristics of this geographical zone, which is featured as the most hyper-arid and cloudless place in the world, make this area a potential target for surface reflectance characterization. Day and night LST comparison between field and remote sensing data are lower than 2?K and the Root Mean Square Error for land surface emissivity is close to 2%. This work opens the possibilities to consider the Atacama Desert as a reference target for calibration and validation activities for earth observation missions’ purposes.  相似文献   

Transgressive dunefield landforms and vegetation associations,Doña Juana,Veracruz, Mexico     

Patrick Hesp  Marisa Martinez  Graziela Miot da Silva  Natalia Rodríguez‐Revelo  Erika Gutierrez  Adriana Humanes  Daniela Laínez  Irene Montaño  Verónica Palacios  Agustín Quesada  Lorena Storero  Gabriela González Trilla  Carolina Trochine 《地球表面变化过程与地形》2011,36(3):285-295

Transgressive dune fields often comprise a multiplicity of landforms where vegetation processes largely affect landform dynamics, which in turn, also affect vegetation processes. These associations have seldom been studied in detail. This paper examines four separate landform types in a complex coastal transgressive dunefield located in the central Gulf of Mexico, in order to assess the relationships between dunefield habitat, local environmental factors, vegetation associations and landform evolution. Topographic surveys using tape and clinometer were conducted in conjunction with vegetation survey transects at four locations across the Doña Juana dunefield. Vegetation surveys allowed the estimation of relative plant cover of each plant species found along the transects. A large variety of landforms were found at the Doña Juana Dunefield: deflation plains, gegenwalle (counter) ridges, transverse dune trailing ridges, blowouts and parabolic dunes, aklé (fish‐scale shaped) dunefields and precipitation ridges, with plant species associations developing on these different landforms equally variable. Flood tolerant species were located in the lower parts (deflation plain and gegenwalle ridges) whereas the older and dryer parts were covered by coastal matorral shrubs. Burial‐tolerant species were dominant in the most mobile areas (blowouts and aklé dunefield and margin). The dune trailing ridge, with relatively milder conditions, showed the highest richness, with no dominant species. A dual interaction was found such that colonizing species both create and affect topography, and in turn, topography determines vegetation association and succession patterns. In coastal dunes, the vegetation and abiotic environment (namely the different landforms and the inherent micronevironmental variability) interact tightly and generate a complex and highly dynamic biogeomorphic system where substrate mobility and colonization processes reinforce one another in positive feedback. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Mesoarchean (3.0 and 2.86 Ga) host rocks of the iron oxide–Cu–Au Bacaba deposit,Carajás Mineral Province: U–Pb geochronology and metallogenetic implications     

Carolina Penteado Natividade Moreto  Lena V. S. Monteiro  Roberto P. Xavier  Wagner S. Amaral  Ticiano José S. dos Santos  Caetano Juliani  Carlos Roberto de Souza Filho 《Mineralium Deposita》2011,46(7):789-811

The Bacaba iron oxide–copper–gold deposit, situated within a WNW–ESE-striking shear zone in the Carajás Domain, Carajás Mineral Province, is hosted by the Serra Dourada Granite, the Bacaba Tonalite, and crosscutting gabbro intrusions, which were intensely affected by sodic (albite–scapolite), potassic, chloritic, and hydrolytic hydrothermal alteration. This deposit is located 7 km northeast of the world-class Sossego iron oxide–copper–gold deposit and might represent a distal and deeper portion of the same or related hydrothermal system. The U–Pb laser ablation inductively coupled plasma–mass spectrometry data for zircon from a sodically altered sample of the Serra Dourada Granite yielded a 2,860±22 Ma (MSWD=11.5) age. Three samples from the Bacaba Tonalite, including one with potassic alteration and two with Cu–Au mineralization, rendered the 3,001.2±3.6 Ma (MSWD=1.8), 2,990.9±5.8 Ma (MSWD=1.9), and 3,004.6±9 Ma (MSWD=2.2) ages, respectively. The ca. 2.86 and ca. 3.0 Ga ages are interpreted as the timing of the igneous crystallization of the Serra Dourada Granite and the Bacaba Tonalite, respectively, and represent the oldest magmatic events recognized in the Carajás Domain. The Serra Dourada Granite and the Bacaba Tonalite are interpreted to greatly predate the genesis of the Bacaba deposit. A genetic link is improbable in the light of the similarities with the Sossego deposit, which is also hosted by younger ca. 2.76 Ga metavolcano-sedimentary units of the Itacaiúnas Supergroup. In this context, the iron oxide–copper–gold deposits in the southern sector of the Carajás Domain could be mainly controlled by important crustal discontinuities, such as a regional shear zone, rather than be associated with a particular rock type. These results expand the potential for occurrences of iron oxide–copper–gold deposits within the Mesoarchean basement rocks underlying the Carajás Basin, particularly those crosscut by Neoarchean shear zones.  相似文献